Pilot Plant Study to Utilize Waste Brine Generated by Salt Industries
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Keywords

 Sodium chloride, waste brine, magnesium removal, temperature, pyramidal crystal

How to Cite

Farhan Ullah Khan, Majid Mumtaz, & Tehseen Ahmed. (2021). Pilot Plant Study to Utilize Waste Brine Generated by Salt Industries. Journal of Basic & Applied Sciences, 8(2), 386–392. https://doi.org/10.6000/1927-5129.2012.08.02.23

Abstract

Since early 80s, people of Pakistan have been enjoying good quality of salt known as refined salt. Mechanical salt washing is used in many countries to upgrade salt quality. The counter current washing at multiple stages and dewatering by centrifuge improves salt quality. During this process almost 10 to 15% of salt is converted into saturated brine solution containing high amount of sodium chloride, calcium, magnesium, potassium and sulphate. In the current practice most of the salt processers, this brine waste solution is drained. In the present study, a method is modified to utilize this waste brine solution. Brine was treated with calcium oxide and iron chloride to remove some soluble and insoluble impurities. The treated brine is evaporated in a specially constructed jacketed crystallizer connected with a hot water geyser. Heat is transferred through bottom by counter current flow. The temperature is maintained between 55 to 65oC at pH 3-4. The applied study yield the well shaped pyramidal crystals of salt known as Fluer de sel (flower of salt), that are world famous and used in gourmet foods with a growing market. Fleur de Sel has unique morphology, lower bulk density, large surface area, improved taste and rapid dissolution as compared to the common cubic salt

https://doi.org/10.6000/1927-5129.2012.08.02.23
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References

Iliopoulou?G. J, Sorra V, Strogyloudi E, Catsiki V.A, Dimitriou E. An evidence of salinity impact on the bioaccumulation of heavy metals in fishes collected from the Messolonghi lagoon in Greece, Toxicological & Environmental Chemistry, 2001; 81(3-4): 123-31. http://dx.doi.org/10.1080/02772240109359025

Herron N, Davis R, Dawes W, Evans R. Modelling the impacts of strategic tree plantings on salt loads and flows in the Macquarie River Catchment, NSW, Australia, Journal of Environmental Management. 2003; 68: 37–50. http://dx.doi.org/10.1016/S0301-4797(02)00230-X

Kaya C, Higgs D, Kirnak H. The effects of high salinity (NaCl) and supplementary phosphorus and potassium on physiology and nutrition development of Spinach, Bulg. J. Plant Physiol., 2001; 27(3–4): 47–59.

Jhala D.S. (Salt Industry and environment), 8th World Salt Symposium, Vol # 2, Page 1295-6, Edited by Rob. M. Geertman 2000, Elsevier.

Mutaz A. Q. Environmental impacts of water desalination along the coastal region of Israel and the Palestinian authority, In 2nd Israeli-Palestinian International /conference on Water for Life Held in Antalya, Turkey, 10-14 October 2004.

Inoue S, Sugimoto N, Yoshida M, Akoh Kaisui Corporation 974-Katoh, Kariya, Akoh City, hyogo Prefecture, Japan. (Manufacturing of flaky salt) 8th World Salt Symposium, Vol # 1, page 439-44, Edited by Rob. M. Geertman 2000, Elsevier.

Piotr M, Synowiec, Barbra. Application of crystallization with chemical reaction in the process of waste brine purifying in evaporative Sodium Chloride, Ind. Eng. Chem Res, 2005; 44: 2273-80. http://dx.doi.org/10.1021/ie040118e

Meijer J.A.m, Leeuw K.J. (Salt recovery from waste brine and waste salt) 8th World Salt Symposium, Vol # 1, page 595-8, Edited by Rob. M. Geertman 2000, Elsevier.

Richard R.M. Project Engineer, International Salt Company Clarks Summit, Pa. (Higher Raw Brine Purity from Rock Salt) Third Symposium on Salt. Page 155-61, Vol # 2, 1970 (April 22-24, 1969, Clevenland OH).

Zhou X, Xia C. Study on the salt crystallization behaviors during bittern boiling evaporation at 70oC, 9th International Symposium on Salt, Vol. # 2, Page 1182-8. Edited by Sha Zuoliang, 2009, Published by Gold Wall Press.

Donadio C, Bialecki A, Valla A, Dufossé L. Carotenoid-derived aroma compounds detected and identified in brines and speciality sea salts, such as salt flowers, produced in solar salterns from Saint-Armel (France). Journal of Food Composition and Analysis, 2011; 24: 801-10. http://dx.doi.org/10.1016/j.jfca.2011.03.005

Umer A, Hussain S.I, Akhter J. Design of Salt Refining Plant, A thesis to fulfill the requirement of Degree of Engineering. Department of Mechanical Engineering, N.E.D University of Engineering and Technology Karachi 1984.

Sedivey V. (Processing of salt for chemical and human consumption), 9th World Salt Symposium, Vol #2, page 1479-83, Edited by Sha Zuoling, Gold Wall Press Year?.

GIS data of Salt Micronutrient Initiative of Pakistan (http://pakusi.naqsha.net).

Meijer J. A. M, Leeuw K. J. (Salt recovery from waste brine and waste salt), 8th World Salt Symposium, Vol #1, page 595-8, Edited by Rob. M. Geertmanm, 2000, Elsevier.

Balarew C, Rabadjieva D, Tepavitcharova S. (Improve Treatment of Waste Brines), 8th World Salt Symposium, Vol # 1, page 551-4, Edited by Rob. M. Geertman, 2000, Elsevier.

Neptune G. A history of common salt by Robert P. Multhauf. The Jophns Hopkins University Press: ISBN:08018-5469-5: 1996.

Philippe de-F, Muchart. (A new process for the washing of solar salt), The Second Symposium on Salt (SECTION IV. EVAPORATED), sponsored by the Northern Ohio Geological Society, held in Cleveland on May 3-5, 1965.

Sabatin O. (Salt Production and Processing in Jordan), 8th World Salt Symposium, volume 1, page 555-7, Edited by Rob. M. Geertman, 2000, Elsevier.

Harshad M. P. (Factor for optimum brine treatment process design) Olin Corporation Charleston, Tennessee, USA, Sixth Internation Symposium on Salt 1983, Vol 2, page 515-33.

Semerjian L, Ayoub G.M. High-pH–magnesium coagulation–flocculation in wastewater treatment. Advances in Environmental Research, 2003; 7: 389–403. http://dx.doi.org/10.1016/S1093-0191(02)00009-6

British Pharmacopoeia (International Edition), vol. 1 (HMSO, London, 2005), pp-604-605, Method 7647-14-5.