Ambipolar Charge Transport of PCNTC-O and PCNTC-R Cocrystals Obtained Under 1:2 and 1:1 Ratios of Donor and Acceptor
Vol. 18 (2022), Energy
Vol. 18 (2022)

Ambipolar Charge Transport of PCNTC-O and PCNTC-R Cocrystals Obtained Under 1:2 and 1:1 Ratios of Donor and Acceptor

Energy
Published 2022-12-26
Junle Ren
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China and School of Automation, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Zhelin Ding
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China and School of Automation, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Yuyao Li
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China and School of Automation, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Qiqi Mu
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China and School of Automation, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Qiguang Shen
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China and School of Automation, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Shoufeng Zhang
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
Li Zhang
School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545000, Guangxi, China
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Keywords

Charge transport
Bipolar organic semiconductors
D-A cocrystal.

How to Cite

Ren, J. ., Ding, Z. ., Li, Y. ., Mu, Q. ., Shen, Q. ., Zhang, S. ., & Zhang, L. . . (2022). Ambipolar Charge Transport of PCNTC-O and PCNTC-R Cocrystals Obtained Under 1:2 and 1:1 Ratios of Donor and Acceptor. Journal of Basic & Applied Sciences, 18, 147–157. Retrieved from https://set-publisher.com/index.php/jbas/article/view/2447
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Abstract

The efficiency of microelectronic devices depends greatly on the charge transport performance of organic semiconductors. The purpose of this work is to analyze the effect of donor-acceptor (D-A) cocrystals on the charge transport characteristics of organic semiconductors using the Marcus theory of electron transfer combined with kinetic Monte Carlo simulations. For two different cocrystals, sesquikis (benzene-1,2,4,5-tetracarbonitrile) 2-(1,3-benzothiazol-2-yl)-3-(pyren-1-yl)prop-2-eneni-trile(PCNTC-O) and ben-zene-1,2,4,5-tetracarbonitrile 2-(1,3-benzothiazol-2-yl)-3-(pyren-1-yl)pr-op-2-enenitrile(PCNTC-R) cocrystals, were investigated using 2-(benzo[d]-thiazol-2-yl)-3-(pyren-1-yl)acrylonitrile (Py-BZTCN) as the donor and 1,2,4,5-tetracyanobenzene (TCNB) as the acceptor mixed at 1:2 and 1:1 ratios, respectively. According to our calculations, PCNTC-O and PCNTC-R both exhibit bipolar charge transport behaviour with mobilities electron/hole attaining 0.0104/0.1252 and 0.0241/0.0598 cm2/Vs, respectively.

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